Real space origin of temperature crossovers in supercooled liquids.
نویسندگان
چکیده
We show that the various crossovers between dynamical regimes observed in experiments and simulations of supercooled liquids can be explained in simple terms from the existence and statistical properties of dynamical heterogeneities. We confirm that dynamic heterogeneity is responsible for the slowing down of glass formers at temperatures well above the dynamic singularity Tc predicted by mode-coupling theory. Our results imply that activated processes govern the long-time dynamics even in the temperature regime where they are neglected by mode-coupling theory. We show that alternative interpretations based on topographic properties of the potential energy landscape are inefficient ways of describing simple physical features which are naturally accounted for within our approach. We show in particular that the reported links between mode coupling and landscape singularities do not exist.
منابع مشابه
Molecular dynamics studies of heterogeneous dynamics and dynamic crossover in supercooled atomic liquids.
Supercooled liquids near the glass transition exhibit the phenomenon of heterogeneous relaxation; at any specific time, a nominally homogeneous equilibrium fluid undergoes dynamic fluctuations in its structure on a molecular distance scale with rates that are very different in different regions of the sample. Several theoretical and simulation studies have suggested a change in the nature of th...
متن کامل6 J un 1 99 9 Inherent Structure Entropy of Supercooled Liquids
We present a quantitative description of the thermodynamics in a supercooled binary Lennard Jones liquid via the evaluation of the degeneracy of the inherent structures, i.e. of the number of potential energy basins in configuration space. We find that for supercooled states, the contribution of the inherent structures to the free energy of the liquid almost completely decouples from the vibrat...
متن کاملDynamics in supercooled liquids and in the isotropic phase of liquid crystals: A comparison
A comparison is made of the dynamics observed over wide ranges of time and temperature between five supercooled liquids and four isotropic phase liquid crystals that have been previously studied separately. Optical-heterodyne-detected optical Kerr effect ~OHD–OKE! measurements were employed to obtain the orientational relaxation dynamics over time scales from sub-ps to tens of ns. For the super...
متن کاملco nd - m at / 9 90 60 81 6 Ju n 19 99 Inherent Structure Entropy of Supercooled
We present a quantitative description of the thermodynamics in a supercooled binary Lennard Jones liquid via the evaluation of the degeneracy of the inherent structures, i.e. of the number of potential energy basins in connguration space. We nd that for supercooled states, the contribution of the inherent structures to the free energy of the liquid almost completely decouples from the vibration...
متن کاملFragile-to-strong crossover in supercooled liquids remains elusive.
Transport properties of glass forming liquids change markedly around an onset temperature To. For temperatures T above To, these properties depend little with T , while for T < To these properties are super -Arrhenius – varying faster than exponentially in 1/T . Upon lowering temperature significantly further, theory [1] predicts that reversible transport in a supercooled liquid, if it can be o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review. E, Statistical, nonlinear, and soft matter physics
دوره 68 4 Pt 1 شماره
صفحات -
تاریخ انتشار 2003